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Polyetherureas as aqueous binders for Li ion Batteries
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03953C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Garima Saini, Mei J Tan, Maximillian G Stanzione, Ketan P Pancholi, Harini Kumar, Matthew Walker, Charlie Patterson, Massimo Vassalli, Aaron Naden, Oxana V. Magdysyuk, Jiyu Tian, A. Robert Armstrong, Amit Kumar
We report here the application of polyetherureas as a new class of aqueous binder for the LiFePO 4 positive electrode material in lithium-ion batteries. Polyetherureas have been synthesized using a...
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DOI: 10.1039/D5GC03953C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Garima Saini, Mei J Tan, Maximillian G Stanzione, Ketan P Pancholi, Harini Kumar, Matthew Walker, Charlie Patterson, Massimo Vassalli, Aaron Naden, Oxana V. Magdysyuk, Jiyu Tian, A. Robert Armstrong, Amit KumarWe report here the application of polyetherureas as a new class of aqueous binder for the LiFePO 4 positive electrode material in lithium-ion batteries. Polyetherureas have been synthesized using a...
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An Electrochemically Promoted Modular Synthesis of Diverse Glycomimetics via Acyloxyphosphonium Ions
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04739K, PaperYi-Min Jiang, Cheng-Lin Ding, Guizhen Zhang, Hongbao Sun, Jie Liu
The installation of sugar residues can significantly enhance the hydrophilicity, pharmacological activity, and bioavailability of natural products and bioactive compounds. In this study, we developed an electrochemical strategy for the...
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DOI: 10.1039/D5GC04739K, PaperYi-Min Jiang, Cheng-Lin Ding, Guizhen Zhang, Hongbao Sun, Jie Liu
The installation of sugar residues can significantly enhance the hydrophilicity, pharmacological activity, and bioavailability of natural products and bioactive compounds. In this study, we developed an electrochemical strategy for the...
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High energy content bi- and mono-cycloalkane and iso-alkane jet blending mixtures derived from ethanol
DOI: 10.1039/D5GC03955J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Robert A. Dagle, Nickolas Riedel, Zhibin Yang, Johnny Saavedra Lopez, Alia Cooper, Michael Thorson, Louis Edwards Caceres-Martinez, Wan Tang Jeff Zhang, Hilkka I. Kenttämaa, Gozdem Kilaz, Joshua Heyne, Ralph GillespieThe aromatization of ethanol-derived olefinic intermediates provides a route forward to high energy density synthetic aviation fuel (SAF) with favorable O-ring seal swell properties.
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A green and efficient strategy for leaching critical metals from spent LiNixCoyMnzO2 cathodes: Modulating the dielectric SiO2 contact-electro-catalytic activity
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04080A, PaperMan Yang, Shuhao Qin, Youchang Yang, Mingmi Wu, Ting Lei, Yufei Liu, Huiju Shao
Amid the global transition toward carbon neutrality, lithium-ion batteries (LIBs) are experiencing unprecedented demand growth as key energy storage components. Contact-electro-catalysis (CEC) method has been utilized in recycling spent LIBs...
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DOI: 10.1039/D5GC04080A, PaperMan Yang, Shuhao Qin, Youchang Yang, Mingmi Wu, Ting Lei, Yufei Liu, Huiju Shao
Amid the global transition toward carbon neutrality, lithium-ion batteries (LIBs) are experiencing unprecedented demand growth as key energy storage components. Contact-electro-catalysis (CEC) method has been utilized in recycling spent LIBs...
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Green Pathways to Low Sulfur Diesel: Advances and Challenges in Desulfurization Technologies
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04160K, Tutorial ReviewPeiwen Wu, Shaojie Ma, Wenshuai Zhu
Diesel desulfurization is crucial for producing ultra-low sulfur diesel to meet stringent environmental regulations and reduce harmful emissions. Traditional hydrodesulfurization processes, while widely used, face limitations in removing refractory sulfur...
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DOI: 10.1039/D5GC04160K, Tutorial ReviewPeiwen Wu, Shaojie Ma, Wenshuai Zhu
Diesel desulfurization is crucial for producing ultra-low sulfur diesel to meet stringent environmental regulations and reduce harmful emissions. Traditional hydrodesulfurization processes, while widely used, face limitations in removing refractory sulfur...
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An electrochemical azidation of least hindered tertiary and benzylic C(sp3)–H bonds
DOI: 10.1039/D5GC05418D, CommunicationJianyou Zhao, Jiaoyang Liu, Zhe Zhang, Chengling Deng, Shengkang Qian, Zhehuai Liu, Fan Wang, Shuai Liu, Zhong-Quan Liu
We herein report a Cu-electrocatalyzed strategy for selective azidation of tertiary and benzylic C(sp3)–H bonds, affording the corresponding azides in consistently high yields.
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Photo-promoted carbonylative carboxylation of alkenes to synthesize β-alkyl ketocarboxylic acid derivatives with CO and CO2 as two mixed C1 gaseous molecules
DOI: 10.1039/D5GC04231C, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hefei Yang, Le-Cheng Wang, Yuanrui Wang, Xiao-Feng WuHerein, we report a photocatalytic carbonylative carboxylation strategy for alkenes, achieving the cooperative utilization of both CO and CO2 as C1 building blocks within a single reaction system.
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In situ reduction engineering of NiFe–NiFe2O4 heterojunctions for interfacial coupling toward efficient bifunctional zinc–air batteries
DOI: 10.1039/D5GC04845A, PaperYi Hu, Ning Han, Yiting Wu, Cong Han, Lizi He
Tuning the electronic interface in heterostructures yields a high-performance bifunctional oxygen electrocatalyst (ΔE = 0.68 V). The assembled Zn–air batteries show excellent performance, enabling a new path for green electrocatalysts.
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Industry-friendly urea coating by interlocking waste proteins and nanoparticles via a glass transition approach
DOI: 10.1039/D5GC04420K, PaperKanchan Swami, Mona Nagargade, Parul Sharma, Prem Kumar, Bandana Kumari Sahu, Vishal Tyagi, Sarita Kataria, Navjot Singh, Vijayakumar Shanmugam
Densification of feather microfiber at Tg for a stable coating. Graphical abstract image is created with the help of Canva.com.
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Hydrophobic and Mechanically Reinforcing Coatings from Palmitoylated Lignin via Waterborne Spraying
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05423K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jie Wu, Nathan Huang, Daniel Barker-Rothschild, Zhangmin Wan, Minke Yang, Xin Shu, Yi Hu, Joshua R. Booth, Oliver Riley Evenden, Orlando J. Rojas, Kwang Ho Kim
Softwood Kraft lignin was esterified with palmitic anhydride to produce palmitoylated lignin (p-lignin). Structural analyses by FTIR and quantitative 31P NMR confirmed high degrees of hydroxyl substitution (71% aliphatic and...
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DOI: 10.1039/D5GC05423K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jie Wu, Nathan Huang, Daniel Barker-Rothschild, Zhangmin Wan, Minke Yang, Xin Shu, Yi Hu, Joshua R. Booth, Oliver Riley Evenden, Orlando J. Rojas, Kwang Ho KimSoftwood Kraft lignin was esterified with palmitic anhydride to produce palmitoylated lignin (p-lignin). Structural analyses by FTIR and quantitative 31P NMR confirmed high degrees of hydroxyl substitution (71% aliphatic and...
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A porous liquid constructed from single-walled polyoxometalate nanotubes for sustainable extractive–oxidative desulfurization
DOI: 10.1039/D5GC05177K, PaperJing He, Weilai Zhang, Haiyan Huang, Ruyu Cai, Yingxue Cui, Yingcheng Wu, Xiantai Zhou, Huaming Li, Wei Jiang
A unique PWNTs-liquid has been developed, comprising POM-based single-walled nanotubes and a bulky bis-imidazolium-based IL. The PWNTs-liquid could extract thiophene sulfur and convert it into sulfone products with high economic added value.
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Eco-design for the Sustainable Scale-Up of Flexible Transparent Conductive Electrodes at the Early-Stage Development
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03167B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhengyin Piao, Luz Meza, Darpan Shukla, Richard A. Venditti, Yong Zhu, Yuan Yao
Silver nanowires (AgNWs) printed on regenerated cellulose (RC) substrate represent a promising class of flexible transparent conductive electrodes (TCEs), paving the way for a wide range of intelligent applications related...
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DOI: 10.1039/D5GC03167B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhengyin Piao, Luz Meza, Darpan Shukla, Richard A. Venditti, Yong Zhu, Yuan YaoSilver nanowires (AgNWs) printed on regenerated cellulose (RC) substrate represent a promising class of flexible transparent conductive electrodes (TCEs), paving the way for a wide range of intelligent applications related...
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Electrochemical Metal-Free Functionalization of ArCF3: Efficient Construction of C-S, C-Se, C-D, C-H, and C-C Bonds
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05060J, CommunicationZhi min Xu, Zong hao Zhou, Xiaochen Wang, Yu xia Yang, Yi Pan, Yi Wang
Herein, we report an innovative metal-free catalytic electrochemical defluorination method for constructing C-S, C-Se, C-D, C-H, and C-C bonds. This approach offers excellent versatility, starting from simple trifluoroarylbenzene as a...
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DOI: 10.1039/D5GC05060J, CommunicationZhi min Xu, Zong hao Zhou, Xiaochen Wang, Yu xia Yang, Yi Pan, Yi Wang
Herein, we report an innovative metal-free catalytic electrochemical defluorination method for constructing C-S, C-Se, C-D, C-H, and C-C bonds. This approach offers excellent versatility, starting from simple trifluoroarylbenzene as a...
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Simple fabric-to-fibre recycling of PBT/Cotton textile blends using water under mild conditions
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03705K, PaperSimão V. Pandeirada, Paula S. S. Lacerda, Michael A. R. Meier, Andreia F. Sousa
The increasing global demand for textiles has contributed to a rapid rise in textile waste, particularly from hard-to-recycle polymer mixtures such as polyester/cotton blends, posing major challenges to achieve circularity...
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DOI: 10.1039/D5GC03705K, PaperSimão V. Pandeirada, Paula S. S. Lacerda, Michael A. R. Meier, Andreia F. Sousa
The increasing global demand for textiles has contributed to a rapid rise in textile waste, particularly from hard-to-recycle polymer mixtures such as polyester/cotton blends, posing major challenges to achieve circularity...
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Differentiated regulation of mineral interface properties using an eco-friendly polysaccharide depressant for enhanced apatite–dolomite sustainable flotation separation
DOI: 10.1039/D5GC04872A, PaperBin Yang, Jing Li, Jingfeng He, Lingtao Zhu, Shihai Guo, Song Zhang
A biodegradable, environmentally friendly, and highly selectively polysaccharide depressant PG modulates the interfacial properties between apatite and dolomite, thereby enabling the efficient flotation separation of these two minerals.
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Photocatalytic Upcycling of PET into Methane, Hydrogen and High-value Liquid Products
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03562G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Madeline Weisweiller, Adrian Ertl, Cornelia von Baeckmann, Anil Kumar Sihag, Christian M. Pichler, Freddy Kleitz, Dominik Eder, Alexey S. Cherevan
The harmful effects of daily plastic use are increasingly evident, with most waste burned or landfilled, leading to the formation of microplastics that pollute the environment and the food chain....
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DOI: 10.1039/D5GC03562G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Madeline Weisweiller, Adrian Ertl, Cornelia von Baeckmann, Anil Kumar Sihag, Christian M. Pichler, Freddy Kleitz, Dominik Eder, Alexey S. CherevanThe harmful effects of daily plastic use are increasingly evident, with most waste burned or landfilled, leading to the formation of microplastics that pollute the environment and the food chain....
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Direct Electrocatalytic O-O Coupling for Modular Synthesis of Aza-cyclic Peroxides from Paired Oxygen Donors
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04553C, CommunicationCong Yu, Liwei Wang, Xiaotong Bu, Hui Liao, Meng Gao
Organic peroxidic bonds represent privileged scaffolds in both organic and medicinal chemistry. However, direct construction of peroxidic bonds (O-O) remains unreported in synthetic methodology, as conventional strategies rely on preactivated...
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DOI: 10.1039/D5GC04553C, CommunicationCong Yu, Liwei Wang, Xiaotong Bu, Hui Liao, Meng Gao
Organic peroxidic bonds represent privileged scaffolds in both organic and medicinal chemistry. However, direct construction of peroxidic bonds (O-O) remains unreported in synthetic methodology, as conventional strategies rely on preactivated...
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Si-doped γ-Al2O3 from solid-phase grinding for highly efficient one-step production of L, L-lactide
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04167H, PaperMin-Min Wang, Hong Guo, Zheng-Wu Wang, Yu-Quan Yan, Yi-Zhou Zhu, He-Fang Wang
L, L-lactide, the important precursor for biodegradable polylactic acid, has attracted significant attention. The one-step synthesis based on nanoconfinement primarily utilizes porous catalysts to induce the cyclization of L-lactic acid...
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DOI: 10.1039/D5GC04167H, PaperMin-Min Wang, Hong Guo, Zheng-Wu Wang, Yu-Quan Yan, Yi-Zhou Zhu, He-Fang Wang
L, L-lactide, the important precursor for biodegradable polylactic acid, has attracted significant attention. The one-step synthesis based on nanoconfinement primarily utilizes porous catalysts to induce the cyclization of L-lactic acid...
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Rearrangement-driven divergent synthesis: a metal-free tandem annulation for CF3-functionalized 1-(aminomethyl)naphthalen-2-ols and 1-(2-naphthyl)azetidines
DOI: 10.1039/D5GC05046D, CommunicationBin Wang, Zekun Li, Hua Cao
A novel metal- and base-free controllable tandem cyclization/rearrangement strategy for divergent synthesis of CF3-containing 1-(aminomethyl)naphthalen-2-ols and 1-(2-naphthyl)azetidines is established.
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Hydrogen-driven, ATP-dependent biocatalytic reduction of carboxylic acids under non-explosive conditions
DOI: 10.1039/D5GC03751D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marianna Karava, Qian Liang, Elske van der Pol, Margit Winkler, Robert KouristThe reduction of carboxylic acids to alcohols in a hydrogen-driven whole-cell biocatalyst employing carboxylic acid reductases ensures high atom and mass efficiency, enabling a potentially more sustainable route for the synthesis of alcohols.
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