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Oxygen Vacancy-Hydroxyl Frustrated Lewis Pairs Enabling CO2 Cycloaddition for Halogen-Free Synthesis of Cyclic Carbonates

Chemical News - 1 hour 55 min ago
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04831A, PaperChengguang Yue, Jiaxin Li, Mei-Yan Wang, Zhiyi Yang, Tiantian Xiao, Ji Qi, Shouying Huang, Yue Wang, Liang-Nian He, Xinbin Ma
Electronic-grade cyclic carbonates, synthesized via the cycloaddition of CO2 with epoxides, are important reagents widely used as lithium-ion battery electrolytes, polar aprotic solvents, and polymer monomers. However, current manufacturing processes...
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Co-O-Si interface engineering for sustainable ammonia synthesis with nearly 100% Faradaic efficiency

Chemical News - 1 hour 55 min ago
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04243G, PaperWeize Chen, Hui Su, Xuan Zheng, Xiaoping Chen, Jing Tang, Yi Li, Qingxiang Wang, Yun Ling
Electrocatalytic nitrate reduction to ammonia (NO3RR) under ambient conditions offers a sustainable alternative to the traditional Haber-Bosch process. Herein, we develop a silica-templated strategy to construct nanoflower-like CoSiOx catalysts composed...
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Synergistic Enhancement of Evaporation-Driven Power Generation via Thermoelectric Coupling at Elevated Temperatures

Chemical News - 1 hour 55 min ago
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03587B, CommunicationXin Zhou, Changhao Li, Jianfeng Lin, Guang Yang, Zipei Zhang, Zhangfeng Wu, Mi Lu, Jianping Lin
Natural evaporation offers vast emission-free energy. We overcome low power limitations using a novel hybrid evaporative-thermoelectric generator. This sustainable synergy yielded 11.37 W/m2 (31.45% increase) at 100°C with a p-Bi2Te3...
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From Lab-Scale Performance to Field Barriers: Electrocatalytic Nitrate Treatment for Sustainable Water Remediation

Chemical News - 1 hour 55 min ago
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04166J, Tutorial ReviewZhenlin Mo, Wei Guo, Laiji Xu, Yiwen Chen, Shaoqi Zhou, Baojun Liu
Electrocatalytic nitrate reduction (eNO₃RR) offers a promising route for sustainable water remediation coupled with resource recovery, yet the translation from lab-scale catalyst innovation to field-scale implementation faces significant barriers. This...
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Synergistic microwave–metal interactions in polyurethane/biomass co-pyrolysis: unraveling reaction mechanisms and product selectivity control

Chemical News - 1 hour 55 min ago

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03270A, PaperYu Ni, Shanjian Liu, Weiming Yi, Jiyan Ma, Qing Dong, Chengxizi Zhang
Metal-modified biochar catalysts induce microwave–metal synergistic effects during polyurethane–biomass co-pyrolysis. These effects enhance thermal and electromagnetic interactions, promoting the selective formation of nitrogen-containing chemicals.
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ATP-Independent Enzymatic Cascade for Chitin-to-Glucose Bioconversion

Chemical News - 1 hour 55 min ago
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04343C, PaperJin-Da Zhuang, Josef Voglmeir, Jin-Min Shi, Aimin Lu, Li Liu
Chitin, a widely available biomass, was efficiently converted to glucose using a modular multienzyme cascade without requiring ATP. By integrating known metabolic pathways, we designed and assembled a self-sustaining catalytic...
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Membrane-free one-pot cascaded electrocatalytic redox of furfural into gamma-butyrolactone

Chemical News - 1 hour 55 min ago

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03829D, PaperShengqin Liu, Yangxin Jin, Qi Zhu, Xiaodan Xu, Shan Shao, Kartick Chandra Majhi, Qingguo Le, Jieming Huang, Jian Zhang, Zupeng Chen, Jason Chun-Ho Lam
A green and sustainable one-pot paired electrolysis method is introduced for the conversion of furfural (FAL), a biomass-derived platform compound, into gamma-butyrolactone (GBL).
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Green and efficient cell wall nano-reconstruction under ambient temperature towards strong cellulosic aerogels

Chemical News - 1 hour 55 min ago

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03785A, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiaoying Xu, Arezu Sehati, Lukas Marcos Celada, Peter Olsén, Lars Berglund, Yuanyuan Li
A green and efficient approach for synthesizing strong cellulosic aerogels was developed through ambient-temperature wood cell wall nano-reconstruction, with a detailed study of the generation of mesoporosity and lumina nanofibril networks.
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Directional CO spillover promotes C–N coupling for highly selective electrocatalytic urea production

Chemical News - 1 hour 55 min ago

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03681J, PaperSheng Chang, Jing Gao, Yimin Xuan, Kui Wang
The tandem Zn@Cu electrode enables spontaneous CO spillover from Zn to Cu, which boosts the *CO coverage on Cu and facilitates efficient C–N coupling to synthesize urea.
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Correction: Evaluating the possibilities and limitations of the pyrometallurgical recycling of waste Li-ion batteries using simulation and life cycle assessment

Chemical News - 1 hour 55 min ago
Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC90193F, CorrectionOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marja Rinne, Heikki Lappalainen, Mari Lundström
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Constructing a Bi–O–Mo electronic bridge bond and active sites over Bi/Bi2MoO6/Bi24O31Br10 to boost the stepwise transfer of electrons for efficient CO2 photoreduction

Chemical News - 1 hour 55 min ago

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02374B, PaperHuihui Ding, Huanhuan Wu, Jun Ma, Xiang Li, Shuangshuang Huai, Shijian Zhang, Wenbin Ruan, Xiuxiu Huang, Xiufang Wang, Wenjie Xie
A Bi–O–Mo bridge bond was introduced between BMO and BOB interfaces and surface metal active sites were modified. The catalyst accelerates multi-electron photocatalytic reduction processes and reduces the reaction energy barrier for CO2 reduction.
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Sustainable high-efficiency photocatalytic lithium recovery from spent LiFePO4 batteries: green process design and performance validation

Chemical News - 1 hour 55 min ago

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01122A, PaperYinzhuang Fang, Yurong Han, Menglong Yan, Changwen Li, Xiaolong Yan, Jinwei Li, Haowen Wei, Xianbao Wang, Tao Mei
Recycling spent lithium iron phosphate batteries is of great significance for both economic and environmental protection.
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Efficient Oxidative Cleavage of β-O-4 linkage in Lignin Model Compounds Enabled by a Simple Anderson-Type Polyoxometalate

Chemical News - 1 hour 55 min ago
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03832D, PaperDianyong Yang, Shuo Xie, Danqi Wu, Ji Ding, Enting Shi, Pengfei An, Sheng Dai, Li Guo, Zhenshan Hou
In this work, a simple Anderson-type polyoxometalate (POM), (NH4)4[CuMo6O24H6] (hereafter referred to as CuMo6), was utilized. This Anderson-type POM can be synthesized easily through a straightforward procedure. After undergoing a...
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Uniformly crosslinked algal bioplastic with triggerable decomposition in salt water

Chemical News - 1 hour 55 min ago

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02866C, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andrew E. Ashmar, Eric J. Beckman, Susan K. Fullerton-Shirey
Developing more degradable plastics is key to reducing marine pollution and microplastic-related ecological harm.
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Electrochemically relevant physical–chemical properties of tetraalkylammonium salts solutions in the renewable solvent dihydrolevoglucosenone (Cyrene®); electrochemical behaviour of some representative organic molecules

Chemical News - 1 hour 55 min ago

Green Chem., 2025, 27,12659-12671
DOI: 10.1039/D5GC03356J, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.José M. Ramos-Villaseñor, Jessica Sotelo-Gil, Maricarmen P. Flores-Morales, Ruben Vasquez-Medrano, Bernardo A. Frontana-Uribe
Conductivity, viscosity, IR spectroscopy of tetraalkylammonium salts solutions in DLG, and the electrochemical behavior of representative molecules was studied.
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Machine learning-guided engineering of chalcone synthase enables high-selectivity phloretin biosynthesis in yeast

Chemical News - 1 hour 55 min ago

Green Chem., 2025, 27,12602-12612
DOI: 10.1039/D5GC03435C, PaperMei Li, Canyu Zhang, Hui Liang, Boyang Wu, Wenxi Yu, Guangjian Li, Yufei Cao, Wen-Yong Lou
Machine learning-guided engineering of chalcone synthase effectively overcomes substrate promiscuity, enabling highly selective biosynthesis of phloretin in yeast, and provides a framework for the microbial production of high-value natural products.
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Efficient Synthesis of Covalent Organic Frameworks in Supercritical Carbon Dioxide and their Application in Iodine Capture

Chemical News - 1 hour 55 min ago
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05101K, PaperHai Jiang, Shenglin Wang, Bin Zheng, Xiaofang Su, Muhammad Naveed Javed, Hui Hu, Huanjun Xu, Yanan Gao
Covalent organic frameworks (COFs) are commonly synthesized via solvothermal methods at high temperatures for more than 72 hours, utilizing hazardous organic solvents as reaction medium. Here, we propose a methodology...
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Enhanced catalytic aminolysis of polyethylene terephthalate plastic wastes via zeolite acid-base sites regulation

Chemical News - 1 hour 55 min ago
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04043D, PaperXiaoqin Si, Meng Wu, Yifan Niu, Kanglin Hou, Mengping Fan, Xin Liu, Chen Sun, Tianliang Lu
The catalytic aminolysis of polyethylene terephthalate (PET) plastic wastes to the value-added diamine products plays an increasingly significant role in the sustainable environment and energy development. Herein, Na-ZSM-5-70 zeolite was...
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Two-step chemolytic delamination and depolymerization of multilayer laminated packaging films into valuable chemicals

Chemical News - 1 hour 55 min ago
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02780B, PaperKalsoom Jan, Taofeng Lu, Christian Ayafor, YuanQiao Rao, Junho Jeon, Junsi Gu, Maria C. Folgueras, Hsi-Wu Wong, Wan-Ting Grace Chen
The mechanical recycling of multilayer laminated packaging films (MLPFs) is considerably challenging due to their compositional heterogeneity and their diversity in adhesives. To address this challenge, this study uses a...
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External photocatalyst- and additive-free visible light-driven direct benzylic C–H functionalization with 1,2-diketones

Chemical News - 1 hour 55 min ago
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04600A, PaperXiaofeng Yu, Nan Huang, Yuhua Lu, Yanping Huo, Yang Gao, Xianwei Li, Qian Chen
The direct functionalization of benzylic C–H bonds represents a significant synthetic challenge. Herein, we disclose a visible light-driven direct benzylic C–H functionalization using 1,2-diketones as both the hydrogen atom transfer...
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