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Synergistic Visible-Light/Brønsted-Acid Promoted Deconstructive Aminoalkylation of Spiro Dihydroquinazolinones: Modular Synthesis of α-Functionalized Unnatural Amino Acids

Chemical News - 21 October, 2025 - 15:23
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04059K, CommunicationWenpeng Yang, Hongjie Miao, Jia-Yi Li, Xin-Hua Duan, Li-Na Guo
Synergistic visible-light/Brønsted-acid promoted deconstructive aminoalkylation of spiro-dihydroquinazolinones with aromatic amines and ethyl glyoxylate is presented. The photocatalyst-free protocol delivers a variety of unnatural N-aryl αamino esters containing a quinazolin-4(3H)-one fragment...
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Graphitization-engineered biochar for solar-driven nutrient recovery and sustainable biogas slurry valorization

Chemical News - 21 October, 2025 - 15:23
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04612B, PaperZhengming Yang, Zhongfeng An, Zhuochao Wang, Khantaphong Charoenkal, Yang Xu, Taiwen Li, Han Ding, Tianyu Xu, Xuecheng Sun, Shan Lin, Qiang Li, Hongliang Cao
Solar-driven interfacial evaporation using low-cost biochar evaporators presents a sustainable and highly promising strategy for valorizing nutrient-rich biogas slurry.However, progress is hampered by an incomplete mechanistic understanding of how the...
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Organo-Photocatalyzed Deoxygenative Alkylcarboxylation of Olefins with Alcohols and CO2

Chemical News - 21 October, 2025 - 15:23
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04497A, CommunicationZeyou Wang, Yilin Ding, Yuye Lou, Kun Jin, Jihong Liu, Xiujuan Feng, Ming Bao, Xuan Zhang
Herein we report a general protocol of CO2 participated alkylative carboxylation of alkenes under photocatalysis, where alcohols serve as alkyl sources to provide alkyl radicals via a desulfurative process from...
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Electrochemical synthesis of tetralones utilizing platinum nanoparticles as the anode material

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03300D, CommunicationHui Luo, Yan Wang, Yu He, Li Li, Yinfeng Ma, Guohui Wang, Jinhui Yang
This study developed a low-platinum-loading (2.65%) nanoelectrode, enabling the efficient and environmentally friendly electrosynthesis of tetralones from olefins. The proposed method combines cost-effectiveness, excellent substrate universality, and high atom economy.
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Versatile, tunable method for NaNO2/HX (Cl or Br)–mediated radical dihalogenation or nitration of olefins

Chemical News - 21 October, 2025 - 15:23
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04596G, PaperJinglian Nong, Zehui Cao, Qin He, Yangyang Zhang, Jichao Chen, Yaxin Wang
We have developed a versatile, tunable method for NaNO2/HX (Cl or Br)–mediated radical nitration or vicinal dihalogenation of olefins. The method allowed us to synthesize high-added-value vicinal dihalides by using...
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Ultra-fast and Eco-friendly Recycling Process for Spent LIBs Using Deep Eutectic Solvents: Mechanism and Life-Cycle Insight

Chemical News - 21 October, 2025 - 15:23
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03452C, PaperShuang Liu, Shuangjun Li, Xiangkun Elvis Cao, Sungyeol Choi
The accumulation of end-of-life lithium-ion batteries (LIBs) highlights the need for an efficient and environmentally friendly recycling process. Deep eutectic solvents (DESs) have gained significant attention due to their benefits...
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Aliphatic aldehydes as CO surrogates via photocatalyzed hydrogen atom transfer

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03981A, PaperLuna Raineri, Valerio Morlacci, Ana Maria Constantin, Aleksandr Voronov, Giovanni Maestri, Nicola Della Ca’, Luca Capaldo
We propose aliphatic aldehydes as a new class of sustainable CO photosurrogates via decarbonylative photocatalyzed Hydrogen Atom Transfer (HAT).
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SiC nanowire supported Pd for efficient flow hydrogenation of nitroarenes to arylamines

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03554F, PaperAichun You, Weixian Lian, Xianliang Fu, Yuge Fan, Jinni Shen, Xuan Zhao, Li Zhu, Fan Tian, Man Xu
A highly efficient continuous-flow catalytic system for the ambient hydrogenation of nitroarenes to arylamines has been developed over Pd/SiC NWs.
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Systematic life cycle assessment of cobalt-based blue ceramic pigments: evaluating CoAl2O4 and lower-cobalt alternatives

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, 27,12946-12958
DOI: 10.1039/D5GC02709H, PaperAndrei Ungureanu, Antonella Sola, Paolo Neri, Roberto Rosa, Anna Maria Ferrari
This study identifies low-cobalt blue pigments as sustainable alternatives to traditional CoAl2O4, combining a good colouring performance with significantly reduced environmental impacts through Life Cycle Assessment (LCA).
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Photoinduced copper-catalyzed cross-coupling of epoxides and alkynes via radical anions

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03812J, CommunicationChen Yang, Zunsheng Chen, Zhengze Wu, Qihao Zheng, Yuchao Xue, Xiaoyuan Zeng, W. M. W. W. Kandegama, Guozhu Zhang, Rui Guo
A photoinduced copper-catalyzed radical cross-coupling of epoxides and alkynes via radical anions was achieved to construct multisubstituted α-allenols with high regioselectivity.
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Correction: Benign-by-design N-doped carbonaceous materials obtained from the hydrothermal carbonization of sewage sludge for supercapacitor applications

Chemical News - 21 October, 2025 - 15:23
Green Chem., 2025, 27,13145-13146
DOI: 10.1039/D5GC90187A, CorrectionOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhi-Xiang Xu, Xiao-Qiang Deng, Shu Zhang, Ya-Fei Shen, Ya-Qi Shan, Zhan-Ming Zhang, Rafael Luque, Pei-Gao Duan, Xun Hu
The content of this RSS Feed (c) The Royal Society of Chemistry

Direct C–H alkylation, acylation, and silylation of N-heteroarenes enabled by the self-quenching of quinolinones

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04299B, PaperBin Sun, Jianjie Wang, Qian Zhang, Yuanyi Chen, Yan Xu, Xiaohui Zhuang, Chun Lv, Xiao Yang, Weike Su, Can Jin
A sustainable C–H/C–H cross-dehydrogenative coupling strategy has been developed for the direct C–H functionalization of N-heteroarenes.
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Scalable synthesis of 2,5-diformylfuran in single-phase continuous flow and segmented flow

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03392F, PaperMin Jeong Kang, Yea Seul Jang, Chan Pil Park
2,5-Diformylfuran (DFF) was synthesized from carbohydrate-derived feedstocks.
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Chemoselective Minisci alkylation in aqueous medium: a general strategy for functionalization of complex N-heteroarenes and biomolecules

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04621A, PaperQi-Long Hu, Jun-Jie Deng, Jia Ye, Jian Li, Albert S. C. Chan, Hang Su, Xiao-Feng Xiong
An aqueous and photocatalyst-free Minisci alkylation of N-heteroarenes has been developed, enabling the late-stage modification of advanced candidates with complex structures, multiple functional groups and reaction sites.
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Industrial-scale potential valorization of ecotoxicity-free botanical residues: Uncaria laevigata as a high-efficiency corrosion inhibitor for X80 pipeline steel in acid pickling

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, 27,13111-13135
DOI: 10.1039/D5GC03431K, PaperLi Huang, Xinyue Li, Wei Wang, Xianzhao Shao, Xiaohui Ji, Huijing Li, Xiang Nan, Yanchao Wu
X80 pipeline steel easily corrodes during acid pickling.
The content of this RSS Feed (c) The Royal Society of Chemistry

Transforming PET recycling via solar-assisted sorption-enhanced gasification for a circular economy: integrated techno-economic and life cycle assessment

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01106J, PaperShouzhuang Li, Yuming Wen, Yi Fang, Xian Li, Wujun Wang, Lili Zhang, Chi-Hwa Wang, Kevin M. Van Geem, Mika Järvinen
Application of solar-assisted sorption-enhanced gasification technology to convert PET into valuable products in Europe is comprehensively assessed.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Coupling of oxygen vacancies and an anatase/TiO2 (B) phase junction for promoting photocatalytic performance of platinum toward ammonia synthesis

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04170H, CommunicationDi Lei, Jinhan Liu, Xianwei Zhang, Guangming Wang, Yan Wang, Rong Fu
The synergy between oxygen vacancies and Pt species creates an efficient pathway for ammonia synthesis.
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A global analysis of the rise, reign, and retreat of topics in research toward sustainable platform chemicals

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, 27,12985-13003
DOI: 10.1039/D5GC02863A, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Paul Tautorat, Benedetta Tremolada, Antonio J. Martín, Lucas F. Santos, Gonzalo Guillén-Gosálbez, Javier Pérez-Ramírez, Bjarne Steffen
We analyse global research trends in the sustainable production of ammonia, methanol, olefins, and aromatics by integrating topic modelling, generative AI, and expert judgment to analyse over 90 000 research articles spanning three decades.
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Stabilization of a Co(II) site via a Co–O–Fe bridging motif for enhanced electro-oxidation of methanol to formate

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, 27,13030-13040
DOI: 10.1039/D5GC03013G, PaperJialong Lin, Xiaoqian Bai, Bingxue Cheng, Chunqi Yang, Yining Wang, Yifan Zeng, Fengwang Li, Yihua Zhu, Yuhang Li, Tamao Ishida, Guangli Xiu, Toru Murayama, Mingyue Lin
We reveal a Co–O–Fe interface-mediated electron-transfer mechanism: Fe2+ stabilizes Co3+ and inhibits Co4+, promoting formate formation, while the Fe2+/Fe3+ redox cycle sustains the active interface and enhances MOR activity.
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Comprehensive design of phosphide cathodes for seawater electrolysis: from precipitation suppression, high salt resistance, to activity enhancement

Chemical News - 21 October, 2025 - 15:23

Green Chem., 2025, 27,12909-12945
DOI: 10.1039/D5GC03455H, PerspectiveHongxiang Ma, Siqi Wu, Meng Li, Zhenyu Xiao, Xiaobin Liu, Jingqi Chi, Jianping Lai, Lei Wang
This study focuses on TMPs as H2-production catalysts for seawater electrolysis, and asummarize Ca2+/Mg2+ issues, Cl− poisoning, and strategies to enhance TMPs’ HER activity in seawater.
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