Chemical News
Photoredox Catalysis with Pyridinium and Structurally Related Onium Salts: Sustainable Synthesis via Reactive Oxygen Species and Electron Transfer
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03738G, Tutorial ReviewXin-Rong Yao, Jing-Wang Cui, Meng-Ze Jia, Jie Zhang
Pyridinium and its derivatives, which incorporate both redox centers and Lewis acid sites, exhibit high structural tunability. Their excited states can generate singlet oxygen via energy transfer or undergo electron...
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DOI: 10.1039/D5GC03738G, Tutorial ReviewXin-Rong Yao, Jing-Wang Cui, Meng-Ze Jia, Jie Zhang
Pyridinium and its derivatives, which incorporate both redox centers and Lewis acid sites, exhibit high structural tunability. Their excited states can generate singlet oxygen via energy transfer or undergo electron...
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Carrier-free silver carbonate catalysis: In situ conversion of low concentration CO2 in air and actual exhaust gas to oxazolidinones
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04212G, CommunicationPei-Bo Chen, Wang Chen, Jia-Wen Yang, Chan-Cui Wu, Hai-Tao Tang, Ying-Ming Pan, Ying Liang
The increasing concentration of CO₂ in the atmosphere drives global climate change, and efficient methods for CO₂ utilisation are urgently needed. This study introduces a novel carrier-free catalytic approach using...
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DOI: 10.1039/D5GC04212G, CommunicationPei-Bo Chen, Wang Chen, Jia-Wen Yang, Chan-Cui Wu, Hai-Tao Tang, Ying-Ming Pan, Ying Liang
The increasing concentration of CO₂ in the atmosphere drives global climate change, and efficient methods for CO₂ utilisation are urgently needed. This study introduces a novel carrier-free catalytic approach using...
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Low indoor light-driven CO2 conversion into visible C4 bioplastic via homogeneous non-metal-based biohybrids under photoexcitation
DOI: 10.1039/D5GC02437D, PaperWenjing Wang, Mingzhi Zhang, Meng Guo, Jiaxin Wang, Xuelian Wang, Jianheng Yin, Liang Chen, Yaguang Li
A uniformly autotrophic K/O-CN–R. eutropha biohybrid was designed to efficiently convert CO2 into visible C4 bioplastics without the need for any auxiliary agents.
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Sustainable bubble-mediated dynamic triphasic antisolvent crystallization for magnesium sulfate nano-micron particles: Precise size and morphology control
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05730B, PaperYingchen Wang, Sheng Liu, Jiaqi Luo, Mingting Yuan Yuan, Yimin Jia, Qiutong Zhang, Wenhao Yan, Qiushuo Yu
Particle ultrafine processing is an effective strategy for enhancing the physical and chemical properties of materials. However, traditional antisolvent crystallization for ultrafine particle preparation often faces the challenge of uneven...
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DOI: 10.1039/D5GC05730B, PaperYingchen Wang, Sheng Liu, Jiaqi Luo, Mingting Yuan Yuan, Yimin Jia, Qiutong Zhang, Wenhao Yan, Qiushuo Yu
Particle ultrafine processing is an effective strategy for enhancing the physical and chemical properties of materials. However, traditional antisolvent crystallization for ultrafine particle preparation often faces the challenge of uneven...
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From Lignin to Jet Fuel: Advancing Selective Cyclohydrocarbon Production Toward Full Compatibility with Aviation Standards
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04813C, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jianyu Wang, Zheng Li, Chun Zhao, Jing Zhang, Aiguo Wang, Liquan Jing, Na Zhong, Zhangxin Chen, Jinguang Hu
Sustainable aviation fuel (SAF) derived from lignocellulosic biomass represents a critical pathway to decarbonizing the aviation sector. As the only abundant, naturally aromatic biopolymer, lignin offers unique potential for producing...
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DOI: 10.1039/D5GC04813C, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jianyu Wang, Zheng Li, Chun Zhao, Jing Zhang, Aiguo Wang, Liquan Jing, Na Zhong, Zhangxin Chen, Jinguang HuSustainable aviation fuel (SAF) derived from lignocellulosic biomass represents a critical pathway to decarbonizing the aviation sector. As the only abundant, naturally aromatic biopolymer, lignin offers unique potential for producing...
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Strategic Sodium Modulation for Low-Temperature Fabrication of Phase-Pure Na 3 V 2 (PO 4 ) 3 Cathodes: Mechanistic Insights and Performance Optimization in Sodium-Ion Batteries
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05076F, PaperZhaojin Li, Yunbo Di, Zhicheng Wang, Di Zhang, Huilan Sun, Qujiang Sun, Qiujun Wang, Fei Yuan, Ranran Li, Bo Wang
The synthesis of high-purity Na3V2(PO4)3 (NV2P) cathodes is persistently challenged by the formation of Na3V3(PO4)4 (NV3P) impurities and energy-intensive high-temperature processing (>800 °C), which promotes phosphate decomposition and detrimental grain...
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DOI: 10.1039/D5GC05076F, PaperZhaojin Li, Yunbo Di, Zhicheng Wang, Di Zhang, Huilan Sun, Qujiang Sun, Qiujun Wang, Fei Yuan, Ranran Li, Bo Wang
The synthesis of high-purity Na3V2(PO4)3 (NV2P) cathodes is persistently challenged by the formation of Na3V3(PO4)4 (NV3P) impurities and energy-intensive high-temperature processing (>800 °C), which promotes phosphate decomposition and detrimental grain...
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Bi-doped directional spin-polarised electron injection modulates MBene surface d–d coupling to promote nitrogen reduction kinetics
DOI: 10.1039/D5GC04584C, PaperKun Cheng, Shaobin Li, Qingyu Cheng, Li Zhang, Yufeng Jiang, Fengbo Li, Xiaoqing Lv
Bi doping modulates Fe 3d orbital spin, directionally injecting electrons into Mo via d–d hybridization to adjust the Mo d-band center, enhancing ambient electrocatalytic nitrogen fixation for MBene heterostructure.
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Binary Organosolv Strategy for Simultaneous High Yield and Structure Preservation
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05920H, PaperJuntao Wang, Nuno Batalha, Ping Chen, Penghui Yan, Jennifer Adami, Birgitta Elisabeth E. Ebert, Muxina Konarova
Lignin valorization faces a critical trilemma: achieving high recovery yields, preserving labile β-O-4 linkages, and maintaining the process under mild conditions. This study resolves this challenge through an innovative binary...
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DOI: 10.1039/D5GC05920H, PaperJuntao Wang, Nuno Batalha, Ping Chen, Penghui Yan, Jennifer Adami, Birgitta Elisabeth E. Ebert, Muxina Konarova
Lignin valorization faces a critical trilemma: achieving high recovery yields, preserving labile β-O-4 linkages, and maintaining the process under mild conditions. This study resolves this challenge through an innovative binary...
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Low-temperature synthesis of red carbon dots with precise spectral conversion via microwave- solvothermal method and application in spectral conversion film
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05645D, PaperYing Wang, Jiayu Liu, Xinyan Fan, Yonggui Wang, Zefang Xiao, Yanjun Xie
Carbon dots (CDs) are considered effective nanomaterials for photoconversion because of their distinct physical and optical characteristics, especially their ability to reduce aggregation-caused quenching (ACQ). The hydrothermal/solvothermal method is the...
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DOI: 10.1039/D5GC05645D, PaperYing Wang, Jiayu Liu, Xinyan Fan, Yonggui Wang, Zefang Xiao, Yanjun Xie
Carbon dots (CDs) are considered effective nanomaterials for photoconversion because of their distinct physical and optical characteristics, especially their ability to reduce aggregation-caused quenching (ACQ). The hydrothermal/solvothermal method is the...
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Divergent Electrosynthesis of Diketopiperazines and Amides
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05648A, CommunicationAn-Li Long, Qiuhong Liang, Jianjing Yang, Ziping Cao, Kelu Yan, Dan Wang, Jiangwei Wen
The development of convenient and practical synthetic strategies for constructing bioactive diketopiperazines (DKPs) and amide scaffolds without metal residues is of great interest in organic synthesis. Herein, we report a...
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DOI: 10.1039/D5GC05648A, CommunicationAn-Li Long, Qiuhong Liang, Jianjing Yang, Ziping Cao, Kelu Yan, Dan Wang, Jiangwei Wen
The development of convenient and practical synthetic strategies for constructing bioactive diketopiperazines (DKPs) and amide scaffolds without metal residues is of great interest in organic synthesis. Herein, we report a...
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Chemically recyclable, fully biobased polyolefins with performance parity to low-density polyethylene
DOI: 10.1039/D5GC05344G, PaperWei Sun, Yuzhe Pang, Yucheng He, Zhenyang Luo, Puyou Jia, Yonghong Zhou, Ye Sha
We demonstrate a homopolymerization strategy for the controlled synthesis of fully biobased, high-molecular-weight polyolefins. These materials exhibit thermomechanical properties comparable to LDPE while being chemically recyclable.
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A Self-Sufficient Biocatalytic Photo-Fenton System Using Immobilized Glucose Oxidase
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04388C, PaperShifei Kang, Chenjun Lei, Chenjie Ding, Lasse H. Klausen, Bianxiao Cui, Lifeng Cui
As one of the most popular advanced oxidation technologies, Fenton reaction is widely used in industrial wastewater treatment. However, the conventional Fenton process requires continuous H2O2 addition and a highly...
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DOI: 10.1039/D5GC04388C, PaperShifei Kang, Chenjun Lei, Chenjie Ding, Lasse H. Klausen, Bianxiao Cui, Lifeng Cui
As one of the most popular advanced oxidation technologies, Fenton reaction is widely used in industrial wastewater treatment. However, the conventional Fenton process requires continuous H2O2 addition and a highly...
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Visible-Light-Induced Chemoselective Dicarboxylation of Alkynes Using Formate and CO2
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05126F, PaperJiayuan Li, Daoshun Chen, Chanjuan Xi
Visible-light-induced dicarboxylation of alkynes with carbon dioxide (CO2) and formate for the synthesis of succinic acids has been developed. The formate salt acts as both a carboxyl source and reductant...
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DOI: 10.1039/D5GC05126F, PaperJiayuan Li, Daoshun Chen, Chanjuan Xi
Visible-light-induced dicarboxylation of alkynes with carbon dioxide (CO2) and formate for the synthesis of succinic acids has been developed. The formate salt acts as both a carboxyl source and reductant...
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A Switchable Reductive Cyclization of o-Alkyl Nitroarenes: Divergent Synthesis of Heterocycles
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05521K, PaperDingyi Wang, Meiqi Zhu, Hangyu Zhou, You Su, Zheng-Jun Wang, Yikun Chen, Xingyu Xu
A readily accessible o-alkyl nitroarenes have been developed for the divergent synthesis of heterocycles via temperature-controlled, base-mediated reductive cyclization. This protocol enables the rapid and selective transformation of o-alkyl nitroarenes...
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DOI: 10.1039/D5GC05521K, PaperDingyi Wang, Meiqi Zhu, Hangyu Zhou, You Su, Zheng-Jun Wang, Yikun Chen, Xingyu Xu
A readily accessible o-alkyl nitroarenes have been developed for the divergent synthesis of heterocycles via temperature-controlled, base-mediated reductive cyclization. This protocol enables the rapid and selective transformation of o-alkyl nitroarenes...
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Electrochemical reduction of sulfoxides to thioethers with hydrosilanes catalyzed by a recyclable ionic liquid
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05274B, CommunicationZhaoxin Wei, Ziren Chen, Fei Xue, Bin Wang, Yu Xia, Shaofeng Wu, Yonghong Zhang, Weiwei Jin, Xuefeng Jiang, Chenjiang Liu
The first electrochemical reduction of sulfoxides to thioethers has been achieved using a recyclable ionic liquid as both catalyst and electrolyte, without metal catalysts, stoichiometric redox reagents, or external electrolytes....
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DOI: 10.1039/D5GC05274B, CommunicationZhaoxin Wei, Ziren Chen, Fei Xue, Bin Wang, Yu Xia, Shaofeng Wu, Yonghong Zhang, Weiwei Jin, Xuefeng Jiang, Chenjiang Liu
The first electrochemical reduction of sulfoxides to thioethers has been achieved using a recyclable ionic liquid as both catalyst and electrolyte, without metal catalysts, stoichiometric redox reagents, or external electrolytes....
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Engineering Oxygen Vacancies on Ceria via Vanadium Oxide Dispersion for Selective Photocatalytic Cleavage of Lignin C-C Bonds
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05517B, PaperZupeng Chen, Yongqi Zhuang, Yuguo Dong, Yanmei Zheng, Wenjun Zhang, Lin Dong
Lignin, the most abundant natural aromatic polymer on Earth, offers a promising feedstock for the production of value-added aromatic products through selective C-C bond cleavage. However, achieving both high product...
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DOI: 10.1039/D5GC05517B, PaperZupeng Chen, Yongqi Zhuang, Yuguo Dong, Yanmei Zheng, Wenjun Zhang, Lin Dong
Lignin, the most abundant natural aromatic polymer on Earth, offers a promising feedstock for the production of value-added aromatic products through selective C-C bond cleavage. However, achieving both high product...
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Lithium extraction from spinel LiMn2O4 with simultaneous preparation of λ-MnO2 under mild conditions using sodium hypochlorite
DOI: 10.1039/D5GC04585A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yanhui Kong, Yutaro Takaya, Mauricio Córdova-Udaeta, Chiharu TokoroLithium extraction from spinel LiMn2O4 is important because it is both a mainstream LIB cathode and a key precursor for λ-MnO2, which is widely used for selective lithium extraction from brines and seawater.
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Sintering and coking resistant Ni/HTASAO5 catalyst for high temperature dry reforming of methane
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05472A, PaperJiashi Zhu, Xueshuang Wu, Haiqing Cai, Li Li, Jing Yang, Hanyi Liu, Jianli Wang, Guiying Li, Changwei Hu
Dry reforming of methane (DRM) provides a promising strategy for combating global warming by concurrently converting the two greenhouse gases, CH4 and CO2, to value-added syngas. To advance its industrial...
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DOI: 10.1039/D5GC05472A, PaperJiashi Zhu, Xueshuang Wu, Haiqing Cai, Li Li, Jing Yang, Hanyi Liu, Jianli Wang, Guiying Li, Changwei Hu
Dry reforming of methane (DRM) provides a promising strategy for combating global warming by concurrently converting the two greenhouse gases, CH4 and CO2, to value-added syngas. To advance its industrial...
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A Sweet Flow: HMF Production and in-situ Valorization into valuable nitrile-containing compound via Telescopic Flow Chemistry
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04694G, PaperJulian Sánchez Velandia, Mattia. Aannatelli, Cristopher Tinajero, Marcileia Zanatta, Victor Sans, Fabio Aricò, Eduardo Garcia-Verdugo
A biorefinery strategy is reported, applying telescopic flow chemistry for the efficient conversion of sugar-derived biomass, specifically D-fructose, into valuable nitrile-containing compounds. The approach relies on the use of Task-Specific...
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DOI: 10.1039/D5GC04694G, PaperJulian Sánchez Velandia, Mattia. Aannatelli, Cristopher Tinajero, Marcileia Zanatta, Victor Sans, Fabio Aricò, Eduardo Garcia-Verdugo
A biorefinery strategy is reported, applying telescopic flow chemistry for the efficient conversion of sugar-derived biomass, specifically D-fructose, into valuable nitrile-containing compounds. The approach relies on the use of Task-Specific...
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The catalytic conversion of fructose to difructose anhydride
DOI: 10.1039/D5GC04714E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Isabel Hortal-Sánchez, Faysal Ibrahim, Edgard A. Lebrón-Rodríguez, Fabiola Y. Rodríguez-Rodríguez, Grace Gooley, Ruining Ma, Matias Alvear, Ive Hermans, Nelson Cardona-MartínezThe production of difructose anhydride (DFA) from fructose under mild conditions, in a green/bio-derived solvent. Crystal structure created with VESTA, J. Appl. Crystallogr., 2011, 44, 1272–1276.
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