Chemical News
A novel carbon-free 3D porous honeycomb-like MoS2/ReS2 heterostructure with S vacancies as anodes for sodium-ion batteries
DOI: 10.1039/D5GC02014J, PaperMinghui Ding, Siyi Chen, Tianyu Xue, Mingyu Xie, Junying Weng, Dongming Liu, Lechen Diao, Pengfei Zhou
A novel carbon-free 3D porous honeycomb-like MoS2/ReS2-S heterostructure with S vacancies was designed and applied as an anode material for sodium-ion batteries, demonstrating excellent electrochemical performance.
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Tracking the hydrogen spillover of heterogeneous catalysts in hydrogenation: from formation, migration, and regulation to fate
DOI: 10.1039/D5GC02983J, Tutorial ReviewGuangxun Sun, Peng Xue, Lei Wang, Xin Zhang, Guangzheng Sun, Zhidong Wang, Qian Zhang, Peng Zhang, Yunqi Liu, Yuan Pan
The review “Tracking the hydrogen spillover of heterogeneous catalysts in hydrogenation: from formation and fate to regulation” discusses the challenges in structure optimization and offers strategies to enhance hydrogen spillover efficiency.
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A bioinspired heterogeneous catalyst for green and targeted transesterification of ethanol and dimethyl carbonate to ethyl methyl carbonate with high endurance
DOI: 10.1039/D5GC03241E, PaperRongkai Cui, Fengyue Yin, Wangquan Gong, Ningjing Yan, Siyao Li, Changshen Ye, Ting Qiu, Jie Chen
Developing an efficient and sustainable method for producing ethyl methyl carbonate (EMC), a key electrolyte component in lithium-ion batteries, is essential to meet the growing industrial demand and comply with green chemistry principles.
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Green epoxidation of unactivated alkenes via the catalytic activation of hydrogen peroxide by 4-hydroxybenzaldehyde
DOI: 10.1039/D5GC02537K, Paper


An organocatalytic protocol that utilizes 4-hydroxybenzaldehyde as an activator of H2O2 for the epoxidation of unactivated olefins is described. An unprecedented Payne/Dakin tandem mechanistic scenario is presented, supported by DI-HRMS experiments.
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Interfacial molecular engineering-driven self-emulsification: a green strategy for surfactant-free, high-efficiency oral delivery of cyclosporine A
DOI: 10.1039/D5GC02056E, PaperPeiya Shen, Enshi Hu, Jitong Shi, Ruipeng Li, Xingyu Zhu, Yuan Gao, Jianjun Zhang, Yuanfeng Wei, Shuai Qian
A green chemistry strategy for oral peptide delivery using biodegradable cellulose and food-grade trans-anethole enables solvent-free self-emulsification, enhancing bioavailability while minimizing environmental impact and energy use.
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Engineered Pseudomonas putida monoculture system for green synthesis of 7-methylxanthine
DOI: 10.1039/D5GC02883C, PaperBhagya Jayantha, Shuyuan Zhang, Ryan M. Summers, Gamini P. Mendis, Lahiru N. Jayakody
Engineered Pseudomonas putida monoculture efficiently converts caffeine to 7-methylexanthine (7-MX), a clinically proven safe drug for treating myopia.
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Effective and scalable mechanochemical synthesis of platinum(II) heteroleptic anticancer complexes
DOI: 10.1039/D5GC02781K, PaperFatin Rashid, Christopher P. Gordon, Jennette A. Sakoff, Jayne Gilbert, Felipe García, Janice R. Aldrich-Wright
A robust mechanochemical strategy enables rapid and scalable synthesis of platinum(II) anticancer complexes. This greener method reduces solvent use, boosts energy efficiency, cuts costs and promotes sustainable metal complex production.
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Synthesis and characterization of a 3-hydroxybutyrate and 3-hydroxy-9-octadecenoate copolymer from engineered Halomonas
DOI: 10.1039/D5GC02422F, PaperXinyu Chen, Jiangnan Chen, Xu Yan, Qiong Wu, Fuqing Wu, Guo-Qiang Chen
A new copolymer of 3-hydroxybutyrate and 3-hydroxy-9-octadecenoate produced using recombinant Halomonas bluephagenesis is reported. The properties of this copolymer are characterized, and its potential applications are demonstrated.
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Polyphenolic nanomaterials ameliorated salmonellosis via barrier restoration and microbiota regulation
DOI: 10.1039/D5GC01363A, PaperTianyou Wang, Jinhong Dong, Bo Liang, Jianhua Zhang, Weijie Liu, Hengjie Zhang, Lei Yang, Yiwen Li, Xianchun Chen, Zhipeng Gu
Polyphenolic nanomaterials were developed for ciprofloxacin delivery, enhancing antibacterial efficacy while protecting gut health through green synthesis, minimizing side effects, and promoting intestinal barrier and microbiota recovery.
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The importance of ester cleavage in the butylamine pretreatment of hybrid poplar
DOI: 10.1039/D5GC01795E, Paper


Butylamine is an effective in-and-out pretreatment solvent for hybrid poplar. It penetrates the cell walls and breaks ester cross-linkages, facilitating lignin release and improving enzymatic digestion.
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Mechanochemically mediated electrosynthesis: unveiling a new pathway for redox reactions under mechanochemical conditions
DOI: 10.1039/D4GC06293K, Paper


Mechanochemically mediated electrochemistry enables sustainable organic synthesis under slurry/paste conditions, achieving high yields and faster reaction times for aromatic bromide reduction and sulfonamide synthesis with minimal solvent.
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Catalytic Electron-Acceptor Mediated C(sp2)–H Sulfoxidation Reactions
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03110A, PaperWenkai Huang, Xue Yang, Wanting Qi, Yuxin Ding, Chang-Jun Zhang, Yuan-Yuan Xie
In recent years, the formation of catalytic Electron Donor-Acceptor (EDA) complexes has been achieved through electron donor redox cycling. However, an electron acceptor catalyst capable of effectively activating the generation...
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DOI: 10.1039/D5GC03110A, PaperWenkai Huang, Xue Yang, Wanting Qi, Yuxin Ding, Chang-Jun Zhang, Yuan-Yuan Xie
In recent years, the formation of catalytic Electron Donor-Acceptor (EDA) complexes has been achieved through electron donor redox cycling. However, an electron acceptor catalyst capable of effectively activating the generation...
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Strategic Design Principles for Greener Biorefinery: A Substrate-Process Matrix Emphasizing Complete Lignocellulose Utilization over Variant Biomass
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02627J, Critical ReviewJianyu Guan, Aamir Khan, Yi Zhang, Yixing Zhou, Molly Meng-Jung Li, Raffel Dharma Patria, Shao-Yuan Leu
Lignocellulosic biomass (LCB) presents a promising feedstock for sustainable biofuel and bioproduct production. Despite its abundance, only a fraction of LCB is currently utilized, highlighting its complex compositions and the...
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DOI: 10.1039/D5GC02627J, Critical ReviewJianyu Guan, Aamir Khan, Yi Zhang, Yixing Zhou, Molly Meng-Jung Li, Raffel Dharma Patria, Shao-Yuan Leu
Lignocellulosic biomass (LCB) presents a promising feedstock for sustainable biofuel and bioproduct production. Despite its abundance, only a fraction of LCB is currently utilized, highlighting its complex compositions and the...
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Electrochemical Intermolecular Trifluoromethyl-imination of Alkenes
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02920A, CommunicationMeiqun Lu, Kailun Chen, Hu Cai
In this paper, we report the electrochemical trifluoromethyl-imination of olefins in which cheap and readily available sodium triflinate serves as a precursor for the trifluoromethyl radical and imine of diaryl...
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DOI: 10.1039/D5GC02920A, CommunicationMeiqun Lu, Kailun Chen, Hu Cai
In this paper, we report the electrochemical trifluoromethyl-imination of olefins in which cheap and readily available sodium triflinate serves as a precursor for the trifluoromethyl radical and imine of diaryl...
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An innovative microreactor approach for sustainable biodiesel production: process design, continuous purification and comparative LCA
DOI: 10.1039/D4GC06538G, PaperCheng-You Yang, Cheng-Yu Wang, Ni Ni Myint, Yi-Chun Chen, Penjit Srinophakun, Ya-Yu Chiang
A continuous flow microreactor system with a helix wire-based biphasic separator achieves high-purity FAME with reduced waste and energy consumption, as confirmed by LCA, marking a significant advancement in sustainable biofuel processing.
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Non-ionic micelle inspired electrochemical functionalization of diverse NH-heterocycles for the synthesis of β-aminoketones
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01942G, PaperSanjay M. Madurkar, Kuldeep Singh Bhati, Girdhar Pal Singh, Renu Rathore, Dinesh Kumar Yadav, Siddharth Sharma
Alternatives to toxic organic solvents, transition metal, additives and bases are always desirable to reduce its environmental footprint, are now being re-evaluated by developing more sustainable electrolyte free electro-organic synthesis....
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DOI: 10.1039/D5GC01942G, PaperSanjay M. Madurkar, Kuldeep Singh Bhati, Girdhar Pal Singh, Renu Rathore, Dinesh Kumar Yadav, Siddharth Sharma
Alternatives to toxic organic solvents, transition metal, additives and bases are always desirable to reduce its environmental footprint, are now being re-evaluated by developing more sustainable electrolyte free electro-organic synthesis....
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Electrochemical Radical 1,4-Dialkoxylation of 1,3-Dienes to Access (E)-1,4-diethyl Alkenes
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03120F, CommunicationYang'en You, Chenlei Ji, Yuhe Cheng, Zhiwei Jiang
A highly selective 1,4-dialkoxylation of dienes through direct electrolysis under mild reaction conditions has been developed. With widely available alcohol as alkoxyl sources, a variety of Z/E-mixture 1,3-dienes undergo dialkoxylation...
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DOI: 10.1039/D5GC03120F, CommunicationYang'en You, Chenlei Ji, Yuhe Cheng, Zhiwei Jiang
A highly selective 1,4-dialkoxylation of dienes through direct electrolysis under mild reaction conditions has been developed. With widely available alcohol as alkoxyl sources, a variety of Z/E-mixture 1,3-dienes undergo dialkoxylation...
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The critical role of crystal phases of LaPO4 in controlling the acidic sites for the production of 5-hydroxymethylfurfural from glucose
DOI: 10.1039/D5GC01931A, PaperYanjuan Yang, Yuhuan Li, Liang Deng, Shangzhi Xie, Chuang Gao, Zixu Yang, Jing Xu
This work highlights the critical role of LaPO4 crystalline phases in controlling the acidic sites during the conversion of glucose to 5-hydroxymethylfurfural through various characterization techniques and DFT calculations.
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Magnetically recyclable vanadium-substituted phosphotungstic acid in a deep eutectic solvent for effective wheat straw fractionation
DOI: 10.1039/D5GC02476E, PaperXirun Zhao, Gaojin Lyu, Chang Geun Yoo, Zhen Wang, Jiachuan Chen
A magnetically recyclable POM/DES system was developed to effectively fractionate wheat straw, promote enzymatic saccharification of the carbohydrate fraction, and valorize the lignin fraction.
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Engineering anisotropic wettability in metal–organic framework composites for advanced multiphase-interfacial biocatalysis
DOI: 10.1039/D5GC02210J, PaperShenghao Wang, Linbo Cao, Jiasheng Zhang, Yueyuan Luo, Zhenning Guo, Mingmin Li
Design strategy of high-performance immobilized enzymes for liquid–liquid reactions.
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