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A bioinspired heterogeneous catalyst for green and targeted transesterification of ethanol and dimethyl carbonate to ethyl methyl carbonate with high endurance
DOI: 10.1039/D5GC03241E, PaperRongkai Cui, Fengyue Yin, Wangquan Gong, Ningjing Yan, Siyao Li, Changshen Ye, Ting Qiu, Jie Chen
Developing an efficient and sustainable method for producing ethyl methyl carbonate (EMC), a key electrolyte component in lithium-ion batteries, is essential to meet the growing industrial demand and comply with green chemistry principles.
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Green epoxidation of unactivated alkenes via the catalytic activation of hydrogen peroxide by 4-hydroxybenzaldehyde
DOI: 10.1039/D5GC02537K, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Efthymios T. Poursaitidis, Christiana Mantzourani, Ierasia Triandafillidi, Maroula G. Kokotou, Christoforos G. KokotosAn organocatalytic protocol that utilizes 4-hydroxybenzaldehyde as an activator of H2O2 for the epoxidation of unactivated olefins is described. An unprecedented Payne/Dakin tandem mechanistic scenario is presented, supported by DI-HRMS experiments.
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