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Biomimicry of CO2 transfer through a biotin-mediated ATP-free pathway

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02628H, PaperAbdussalam K. Qaroush, Feda'a M. Al-Qaisi, Ala'a F. Eftaiha, Rana T. Abu-Saileek, Khaleel I. Assaf, Alex MacDonald, Philip G. Jessop
The Mukaiyama-carbonic acid (MCA) adduct enables CO2 transfer to sodium pyruvate under mild conditions, offering a promising in vitro route for biotin carboxylation.
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Sustainable upcycling of polyethylene waste to compatibilizers and valuable chemicals

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02799C, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Darien K. Nguyen, Zoé O. G. Schyns, LaShanda T. J. Korley, Dionisios G. Vlachos
Catalyst-free, bulk oxidation of low-density polyethylene (LDPE) can be achieved with non-thermal atmospheric plasma via a viscosity modifier approach, enabling compatibilization in mixed polymer blends.
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Incorporation of lignin into adhesives: a review

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02998H, Critical ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Juan Paez, Pedram Fatehi
This review discusses the recent advancements and challenges associated with the use of lignin in adhesive fabrication.
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Photoelectrochemical dicarboxylation of styrene with CO2 to phenylsuccinic acid on a Ni-decorated silicon photocathode

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03730A, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiaoxue Zhou, Hao Yang, Ziqi Zhao, Hongxia Ning, Yu Shan, Ming Cheng, Peili Zhang, Fei Li, Licheng Sun, Fusheng Li
A Ni-decorated p-type silicon photocathode was developed for photoelectrochemical dicarboxylation of styrene with CO2 to synthesize phenylsuccinic acid. A high Faradaic efficiency of 77.7% for phenylsuccinic acid is achieved at −2.4 V vs. Ag/AgCl.
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SolECOs: a data-driven platform for sustainable and comprehensive solvent selection in pharmaceutical manufacturing

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04176G, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yiming Ma, Shang Gao, Neel Mehta, Qinqing Fu, Wei Li, Brahim Benyahia
SolECOs combines machine learning and sustainability metrics to enable data-driven solvent selection. Validated with four APIs, it delivers robust solubility prediction, sustainability ranking, and crystallization design support.
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Correction: Recycling of anhydride-cured epoxy resin-based carbon fiber-reinforced composites via a β-phenethyl alcohol/TBD catalytic system

Chemical News - 6 ottobre, 2025 - 05:43
Green Chem., 2025, 27,11985-11986
DOI: 10.1039/D5GC90177D, CorrectionOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Renlong Min, Chenyu Zhang, Haijuan Kong, Shuo Liu, Ziyao Peng
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One-pot depolymerization–repolymerization of PET waste into sustainable photocurable liquid copolyesters for high-performance additive manufacturing

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02696B, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rosario Carmenini, Alberto Sanz de León, Tiziana Benelli, Loris Giorgini, Mauro Comes Franchini, Sergio I. Molina, Mirko Maturi
Solvent-free one-pot PET upcycling yields photocurable copolyesters with record mechanical performance and 83% sustainable content for vat photopolymerization.
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Introduction to green and sustainable batteries

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, 27,11559-11560
DOI: 10.1039/D5GC90160J, EditorialCristina Pozo-Gonzalo, Rebeca Marcilla, Maria-Magdalena Titirici, Theresa Schoetz
Cristina Pozo-Gonzalo, Rebeca Marcilla, Maria-Magdalena Titirici and Theresa Schoetz introduce the cross-journal themed collection on Green and Sustainable Batteries.
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Low-temperature modified-immersion molten ZnCl2-carbonization and activation for continuous production of mesoporous carbon from plastic waste

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02465J, PaperTheerawat Waiyaka, Rungkiat Nganglumpoon, Chonticha Rajrujithong, Weerachon Tolek, Pui Vun Chai, Masayuki Shirai, Anuchit Wuttitrairat, Paisan Kittisupakorn, Joongjai Panpranot
We developed a prototype continuous MSCA system using a modified-immersion ZnCl2 molten salt process at 350 °C to convert common plastic waste (PP, PLA, and PET) into high-surface-area mesoporous carbon for energy storage applications.
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Maximized lipase-catalysed production of a monoester of ferulic acid derivatives and ethylene glycol: a key step toward intrinsically antioxidant biosourced polymers

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, 27,11892-11902
DOI: 10.1039/D5GC02821C, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Felipe D. Blanco, Melissa P. M. Geevers, Ulf Hanefeld, Jean-Luc Six, Latifa Chebil, Catherine Humeau, Yann Guiavarc'h
Original, enzymatic and selective solvent-free approach to produce the monoester ethylene glycol hydroferulate, a monomer precursor toward intrinsically antioxidant polymers.
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Acidic CO2 electroreduction to formic acid at low overpotentials over Cu modified with a dual site polymer

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03348A, PaperYajuan Wang, Zijun Zhang, Chunjun Chen, Yingxuan Liu, Yichi Zhang, Mingjie Cheng, Xia Bai, Shuaiqiang Jia, Mingyuan He, Haihong Wu, Buxing Han
The FE of HCOOH was enhanced over commercial Cu by the modification with a dual site polymer under acidic conditions. The quaternary ammonium cation promoted CO2 reduction at low potentials, the tertiary amine stabilized the key intermediate *OCHO.
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Green solvents in membrane separation: progress, challenges, and future perspectives for sustainable industrial applications

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, 27,11705-11738
DOI: 10.1039/D5GC03161C, Critical ReviewBoon Kee Voon, Yen Juin Yap, Wai Fen Yong
Green chemistry and engineering play a vital role in sustainable separation and technology developments.
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Recent advances in biodegradable polymer blends and their biocomposites: a comprehensive review

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, 27,11656-11704
DOI: 10.1039/D5GC01294E, Critical ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kehinde Olonisakin, Amar K. Mohanty, Mahendra Thimmanagari, Manjusri Misra
Integrating biodegradable polymer blends, compatibilization strategies, and filler reinforcement to develop biodegradable composites for sustainable applications.
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Review on sequential catalysis for higher alcohols: overcoming barriers in direct CO2 hydrogenation

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, 27,11607-11655
DOI: 10.1039/D5GC03160E, Critical ReviewAbdulaziz A. M. Abahussain, Fahd A. Nasr, Ahmed S. Al-Fatesh, Padmanabhan Sambandam, Mohammed Al-zharani, Fekri Abdulraqeb Ahmed Ali, Nadavala Siva Kumar, Sulaiman A. Alsalamah, Ganesan Subbiah, Guganathan Loganathan, Saravanan Palanivelu, Shoba Gunasekaran, Kavitha Chandrasekaran, Tamizhdurai Perumal
Rising CO2 emissions intensify global warming, demanding innovative mitigation. Converting CO2 into higher alcohols offers a renewable path to sustainable fuels and chemicals, addressing greenhouse gases while supporting energy and industrial needs.
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De novo biosynthesis of zeaxanthin and 3-hydroxy-β-ionone by engineered Yarrowia lipolytica

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01415H, PaperXin-Liang Chen, Lei Wang, Ying-Ying Wu, Laijiayun Jin, Xin Feng, Yu-Yue Ma, Hao Liu, Qiang Hua, Ze-Jian Wang, Liu-Jing Wei
Zeaxanthin and its derivatives have an increasing market demand owing to their strong antioxidant, anti-cancer, and anti-inflammatory properties.
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Natural product driven redox-recovery of lithium cobalt oxide cathodes under mild conditions

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03826J, PaperChang-Lian Xu, Xinlei Ji, Honghao Zhang, Xiaoxun Xu, Lilin Wang, Guiyin Wang, Guochun Lv, Xin Qi, Junzhuo Cai, Shirong Zhang, Zhanbiao Yang, Zhang Cheng, Lin Kong, Yaoyuan Zhang
A sustainable closed-loop process is proposed for efficient and selective metal recovery under mild conditions; utilizing the natural amino acid cysteine as a leaching agent, and using the natural oxalic acid as a selective recovery reagent of Co.
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Direct C(sp3)–H chloromethylation through CH2Cl2 activation using non-thermal plasma

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, 27,11857-11869
DOI: 10.1039/D5GC02405F, PaperFabian Bruel, Gabriel Morand, Stéphanie Ognier, Pierre Dedieu, Alain Favre-Réguillon, Cyril Ollivier, Louis Fensterbank, Michael Tatoulian
Catalyst-free chloromethylation of alkanes is achieved via non-thermal plasma activation of CH2Cl2 under ambient conditions. A 30% yield of chlorinated products from cyclohexane is obtained in 60 s. A radical mechanism has been proposed.
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Assessment of the environmental and human health impact in the synthesis and processing of metal halide perovskite active layers using GVL

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, 27,11903-11913
DOI: 10.1039/D5GC03582A, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Filippo Campana, Daniela Lanari, Filippo De Angelis, Luigi Vaccaro
Metal halide perovskites (MHPs) offer a potential alternative to crystalline silicon solar cells in terms of efficiency.
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Adding value to terpenoids: from pseudoionone to 1-methyl-1,3-cyclohexadiene

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, 27,11809-11815
DOI: 10.1039/D5GC03364K, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alexandre Damiani, Lars Faber, Batoul Karim, Christian Bruneau, Wagner A. Carvalho, Dalmo Mandelli, Cédric Fischmeister
Pseudoionone, obtained from citral, is transformed into 1-methyl-1,3-cyclohexadiene in 31% yield by ring closing metathesis, while 63% yield is achieved using a stereoisomer prepared from neral.
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Heterogeneous Fe single-atom catalysis for C2–H amidation of pyridine/quinoline N-oxides: streamlined synthesis of pharmaceutical scaffolds

Chemical News - 6 ottobre, 2025 - 05:43

Green Chem., 2025, 27,11882-11891
DOI: 10.1039/D5GC03797B, PaperJinhua Ou, Song Yu, Duoduo Liu, Han Jiang, Can Lyu, Keyi Chen, Jie Li, Zhuobin Yu, Kaijian Liu, Jinxuan Liu
This first heterogeneous catalytic system enables base/additive-free C2–H amidation of N-oxides with 100% atom economy for pharmaceutical synthesis.
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